Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]−: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes-Reference-Cited by-同舟云学术

Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]−: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes

Published:2016 Issue:32 Volume:45 Page:12691-12701
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Thirumoorthi Ramalingam¹²³⁴,Chivers Tristram¹²³⁴,Häggman Susanna¹⁵⁶⁷,Mansikkamäki Akseli¹⁵⁶⁷,Morgan Ian S.¹⁵⁶⁷,Tuononen Heikki M.¹⁵⁶⁷,Lahtinen Manu¹⁵⁶⁷,Konu Jari¹⁵⁶⁷

Affiliation:

1. Department of Chemistry

2. University of Calgary

3. Calgary

4. Canada

5. University of Jyväskylä

6. Jyväskylä

7. Finland

Abstract

Structural isomerism: formation of a labile tridentate sulfur-ligand led to the isolation of the first examples of O_hand SP Ni(ii) isomers of the same ligand in [Ni{S(H)C(PPh₂S)₂}₂] and their fluxional behaviour is examined.

Funder

Suomen Akatemia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02565J

Reference65 articles.

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5. Bis-phosphorus stabilised carbene complexes

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