Reactivity difference in the oxidative nucleophilic reaction of peroxonickel(iii) intermediates with open-chain and macrocyclic systems-Reference-Cited by-同舟云学术

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Reactivity difference in the oxidative nucleophilic reaction of peroxonickel(iii) intermediates with open-chain and macrocyclic systems

Published:2019 Issue:8 Volume:6 Page:2112-2117
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Yun Seonggeun¹²³⁴,Kwon Nam¹²³⁴,Kim Seonghan¹²³⁴,Jeong Donghyun¹²³⁴,Ohta Takehiro⁵⁶⁷⁸⁹^ORCID,Cho Jaeheung¹²³⁴^ORCID

Affiliation:

1. Department of Emerging Materials Science

2. DGIST

3. Daegu 42988

4. Korea

5. Picobiology Institute

6. Graduate School of Life Science

7. University of Hyogo

8. Hyogo 678-1297

9. Japan

Abstract

The open-chain peroxonickel(iii) intermediate is much more reactive than the macrocyclic analogue in aldehyde deformylation.

Funder

National Research Foundation of Korea

Ministry of Science, ICT and Future Planning

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QI/C9QI00465C

Reference38 articles.

1. Molecular Designs for Controlling the Local Environments around Metal Ions

2. Spectroscopic and computational insight into the activation of O2 by the mononuclear Cu center in polysaccharide monooxygenases

3. Developing Mononuclear Copper–Active-Oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

4. Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

5. A Balancing Act: Stability versus Reactivity of Mn(O) Complexes

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1. Appended Lewis Acids Enable Dioxygen Reactivity and Catalytic Oxidations with Ni(II);Journal of the American Chemical Society;2024-04-25

2. Bio-inspired mononuclear nonheme metal peroxo complexes: Synthesis, structures and mechanistic studies toward understanding enzymatic reactions;Coordination Chemistry Reviews;2023-04

3. A Mononuclear Non-heme Iron(III)–Peroxo Complex with an Unprecedented High O–O Stretch and Electrophilic Reactivity;Journal of the American Chemical Society;2021-09-16

4. Negative catalysis / non-Bell-Evans-Polanyi reactivity by metalloenzymes: Examples from mononuclear heme and non-heme iron oxygenases;Coordination Chemistry Reviews;2021-07

5. A comprehensive insight into aldehyde deformylation: mechanistic implications from biology and chemistry;Organic & Biomolecular Chemistry;2021

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