Silicon-fluorine chemistry: from the preparation of SiF2to C–F bond activation using silylenes and its heavier congeners-Reference-Cited by-同舟云学术

Silicon-fluorine chemistry: from the preparation of SiF2to C–F bond activation using silylenes and its heavier congeners

Published:2018 Issue:40 Volume:54 Page:5046-5057
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sen Sakya S.¹²³⁴^ORCID,Roesky Herbert W.⁵⁶⁷⁸^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis Division

2. CSIR-National Chemical Laboratory

3. Pune 411008

4. India

5. Institute of Inorganic Chemistry

6. Georg-August University

7. Goettingen

8. Germany

Abstract

The feisty nature of silicon(ii) fluorides has been harnessed by two cyclic alkyl amino carbene (cAAC) ligands and (cAAC)₂SiF₂has been isolated at room temperature and structurally characterized.

Funder

Science and Engineering Research Board

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC01816B

Reference105 articles.

1. Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond

2. A Fairly Stable Crystalline Silanone

3. Silicon and Oxygen’s Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene

4. The First Isolable Dialkylsilylene

5. A Remarkable Base-Stabilized Bis(silylene) with a Silicon(I)-Silicon(I) Bond

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