Cationic vacancies accelerate the generation of CoOOH in perovskite hydroxides for the electrooxidation of biomass

Author:

Peng Rixin1,Jiang Yimin1,Dong Chung-Li2ORCID,Thuy Nga Ta Thi2,Lu Yuxuan1,Li Shengkai1,Fan Yun1,Xie Chao13ORCID,Wang Shuangyin1ORCID,Zou Yuqin1ORCID

Affiliation:

1. State Key Laboratory of Chemo/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha 410082, China

2. Department of Physics, Tamkang University, New Taipei City 25137, Taiwan

3. Shenzhen Institute of Hunan University, Shenzhen 518057, China

Abstract

SnCo(OH)6 with abundant Sn cation vacancies facilitates the production of deprotonated Co(OH)2 active species and the adsorption of HMF molecules; the onset potential of HMF oxidation is advanced by 200 mV compared to pristine SnCo(OH)6.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Natural Science Foundation of Hunan Province

Shenzhen Science and Technology Innovation Program

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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