The effect of ligand symmetry on the ratiometric luminescence characteristics of lanthanides
Author:
Affiliation:
1. Department of Applied Chemistry
2. Tokyo University of Science
3. Tokyo 162-8601
4. Japan
5. Department of Chemistry
6. Precursory Research for Embryonic Science and Technology (PRESTO)
Abstract
Nona-coordinated europium(iii) complexes incorporating unsymmetrical β-diketonate ligands exhibit distinctive ratiometric spectral changes within the extremely narrow f–f transition bands in response to temperature changes over the range from 253 to 323 K.
Funder
Japan Science and Technology Agency
Japan Science and Technology Corporation
Japan Society for the Promotion of Science
Asahi Glass Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00898A
Reference52 articles.
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2. Europium complexes with organic ligands containing oxygen as donor atom
3. Interpretation of europium(III) spectra
4. Europium luminescence lifetimes and spectra for evaluation of 11 europium complexes as aqueous shift reagents for nuclear magnetic resonance spectrometry
5. Luminescence and structure of europium compounds
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