Synthesis and coordination chemistry of enantiopure t-BuMeP(O)H

Author:

Gallen Albert12345ORCID,Orgué Sílvia6789,Muller Guillermo12345ORCID,Escudero-Adán Eduardo C.1011129ORCID,Riera Antoni67891ORCID,Verdaguer Xavier67891ORCID,Grabulosa Arnald12345ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica

2. Secció de Química Inorgànica

3. Universitat de Barcelona

4. Martí i Franquès

5. Barcelona

6. Institute for Research in Biomedicine (IRB-Barcelona)

7. The Barcelona Institute of Science and Technology

8. Barcelona 08028

9. Spain

10. Institute of Chemical Research of Catalonia (ICIQ)

11. The Barcelona Institute of Science and Technology (BIST)

12. Av. Països Catalans 16

Abstract

Enantioselective synthesis of t-BuMeP(O)H and its coordination chemistry towards several transition metals are described, showing a variety of coordination modes.

Funder

Ministerio de Economía y Competitividad

Institute for Research in Biomedicine

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference82 articles.

1. Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications , ed. A. Börner , Wiley-VCH , Weinheim , 2008

2. Phosphorus(iii) Ligands in Homogeneous Catalysis: Design and Synthesis , ed. P. C. J. Kamer and P. W. N. M. van Leeuwen , Wiley , 2012

3. THE PHOSPHINOUS ACID (CF3)2POH AND THE DIPHOSPHOXANE (CF3)2POP(CF3)21

4. Stable phosphinous acids

5. Bis(trifluoromethyl)phosphinous Acid (CF3)2P-O-H: An Example of a Thermally Stable Phosphinous Acid—Synthesis, Gas-Phase Structure, and Rotational Isomers

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