Synthesis and properties investigation of hydroxyl functionalized polyisoprene prepared by cobalt catalyzed co-polymerization of isoprene and hydroxylmyrcene

Author:

Xu Yuechao12345,Zhao Junyi12345,Gan Qiao12345,Ying Weilun12345,Hu Zhonghan12345,Tang Fuming12345,Luo Wanwei12345,Luo Yunjie12345ORCID,Jian Zhongbao678910ORCID,Gong Dirong12345ORCID

Affiliation:

1. State Key Laboratory Base of Novel Functional Materials and Preparation Science

2. Ningbo Key Laboratory of Specialty Polymers

3. Faculty of Materials Science and Chemical Engineering

4. Ningbo University

5. Ningbo 315211

6. State Key Laboratory of Polymer Physics and Chemistry

7. Changchun Institute of Applied Chemistry

8. Chinese Academy of Sciences

9. Changchun 130022

10. China

Abstract

Controlled copolymerization of isoprene and hydroxylmyrcene afforded well-defined hydroxyl functionalized polyisoprene. Blends of functionalized polyisoprene/SiO2 displayed enhanced miscibility, and remarkable vulcanization and mechanical properties.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference51 articles.

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3. D. Threadingham , W.Obrecht , W.Wieder , G.Wachholz and R.Engehausen , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , Leverkusen , 2011

4. Late-Metal Catalysts for Ethylene Homo- and Copolymerization

5. Copolymerization of Silyl Vinyl Ethers with Olefins by (α-diimine)PdR+

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