Aerobic oxidative acylation of nitroarenes with arylacetic esters under mild conditions: facile access to diarylketones

Author:

Li Jiang-Sheng12345ORCID,Yang Qian12345,Yang Fan67512,Chen Guo-Qin12345,Li Zhi-Wei12345,Kuang Yin-Jie12345,Zhang Wei-Jing12345,Huang Peng-Mian12345

Affiliation:

1. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation

2. School of Chemistry and Biological Engineering

3. Changsha University of Science & Technology

4. Changsha 410114

5. P.R. China

6. SINOPEC Baling Petrochemical Company

7. Yueyang 414014

Abstract

A regioselectivet-BuONa-mediated aerobic oxidative acylation of nitroarenes under mild conditions is developed through a cascade CDC/oxidative decarboxylation process.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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