Two-bond 13C–13C spin-coupling constants in saccharides: dependencies on exocyclic hydroxyl group conformation-Reference-Cited by-同舟云学术

Two-bond 13C–13C spin-coupling constants in saccharides: dependencies on exocyclic hydroxyl group conformation

Published:2021 Issue:40 Volume:23 Page:22912-22922
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lin Jieye¹,Meredith Reagan J.¹,Oliver Allen G.²^ORCID,Carmichael Ian³^ORCID,Serianni Anthony S.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA

2. Molecular Structure Facility, University of Notre Dame, Notre Dame, IN 46556-5670, USA

3. The Radiation Laboratory, University of Notre Dame, Notre Dame, IN 46556-5670, USA

Abstract

13C-Labeled mono- and disaccharides were studied by X-ray crystallography and solid-state 13C NMR to determine the dependence of 2JC1,C3 in aldopyranosyl rings on the C1–C2–O2–H torsion angle, θ2, involving C2 of the C1–C2–C3 coupling pathway.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03320D

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