Examining the role of Rh/Si cooperation in alkene hydrogenation by a pincer-type [P2Si]Rh complex
Author:
Affiliation:
1. Department of Chemistry
2. Carleton College
3. Northfield
4. USA
5. Department of Chemistry and Biochemistry
6. St. Catherine University
7. St. Paul
Abstract
A bis(phosphine)/triflatosilyl pincer-type Rh(i) complex can reversibly store one equivalent of H2 across the Si–Rh bond upon triflate migration from silicon to rhodium.
Funder
American Chemical Society Petroleum Research Fund
Camille and Henry Dreyfus Foundation
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00027D
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