Regio- and stereoselective syntheses of chiral α-quaternary (<i>Z</i>)-trisubstituted allylic amino acids<i>via</i>synergistic Pd/Cu catalysis-Reference-Cited by-同舟云学术

Regio- and stereoselective syntheses of chiral α-quaternary (Z)-trisubstituted allylic amino acidsviasynergistic Pd/Cu catalysis

Published:2023 Issue:18 Volume:59 Page:2632-2635
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ke Miaolin¹^ORCID,Yu Yuyan¹,Sun Longwu¹,Li Xinzhi¹,Cao Qianqian¹,Xiao Xiao¹^ORCID,Chen Fener¹²³^ORCID

Affiliation:

1. Institute of Pharmaceutical Science and Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China

2. Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, People's Republic of China

3. Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, Shanghai 200433, People's Republic of China

Abstract

Synergistic palladium/copper catalysis for asymmetric allylic alkylation of vinylethylene carbonates with aldimine esters has been developed for the synthesis of α-quaternary (Z)-trisubstituted allylic acids with high efficiency under mild conditions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06820F

Reference60 articles.

1. Inhibition of Proteasome Activities and Subunit-Specific Amino-Terminal Threonine Modification by Lactacystin

2. Total Synthesis of (-)-Altemicidin: A Novel Exploitation of the Potier-Polonovski Rearrangement

3. Marizomib sensitizes primary glioma cells to apoptosis induced by a latest-generation TRAIL receptor agonist

4. Carbidopa: a selective Ah receptor modulator (SAhRM)

5. The lysine pathway as a target for a new genera of synthetic antibacterial antibiotics?

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