Controlled monodefluorination and alkylation of C(sp<sup>3</sup>)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity-Reference-Cited by-同舟云学术

Controlled monodefluorination and alkylation of C(sp³)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity

Published:2022 Issue:47 Volume:13 Page:14090-14100
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kynman Amy E.¹²^ORCID,Elghanayan Luca K.¹,Desnoyer Addison N.¹^ORCID,Yang Yan³,Sévery Laurent¹,Di Giuseppe Andrea¹^ORCID,Tilley T. Don¹^ORCID,Maron Laurent³^ORCID,Arnold Polly L.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720-1460, USA

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

3. LPCNO, Université de Toulouse, 135 Avenue de Rangueil, 31077 Toulouse, France

Abstract

The controlled functionalization of a single fluorine in a CF3 group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.

Funder

H2020 European Research Council

National Institutes of Health

Basic Energy Sciences

Lawrence Berkeley National Laboratory

University of Edinburgh

Engineering and Physical Sciences Research Council

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry