Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion-Reference-Cited by-同舟云学术

Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

Published:2020 Issue:9 Volume:10 Page:2970-2985
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Ochoa Elba¹²³⁴,Henao Wilson¹²³⁴^ORCID,Fuertes Sara⁵⁶⁷⁸⁹^ORCID,Torres Daniel¹²³⁴^ORCID,van Haasterecht Tomas¹⁰¹¹¹²¹³,Scott Elinor¹⁰¹¹¹²¹³^ORCID,Bitter Harry¹⁰¹¹¹²¹³^ORCID,Suelves Isabel¹²³⁴^ORCID,Pinilla Jose Luis¹²³⁴^ORCID

Affiliation:

1. Instituto de Carboquímica

2. CSIC

3. 50018 Zaragoza

4. Spain

5. Departamento de Química Inorgánica

6. Facultad de Ciencias

7. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

8. CSIC – Universidad de Zaragoza

9. Zaragoza

10. Biobased Chemistry and Technology

11. Wageningen University

12. Wageningen

13. Netherlands

Abstract

Evaluation of the dispersion of Pd active sites on the catalyst performance during fatty acids decarbonylation to α-olefins was explored in this work. Pd subnanometric particles, clusters and aggregates were found to modulate the catalyst activity.

Funder

European Regional Development Fund

Secretaría de Estado de Investigación, Desarrollo e Innovación

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY00322K

Reference66 articles.

1. Applications of light olefin oligomerization to the production of fuels and chemicals