Enhanced activity of bulky N-heterocyclic carbenes in nickel–NHC catalyzed Kumada–Corriu cross-coupling of aryl tosylates-Reference-Cited by-同舟云学术

Enhanced activity of bulky N-heterocyclic carbenes in nickel–NHC catalyzed Kumada–Corriu cross-coupling of aryl tosylates

Published:2022 Issue:24 Volume:12 Page:7275-7280
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kardela Marlena¹,Halikowska-Tarasek Katarzyna¹,Szostak Michal²^ORCID,Bisz Elwira¹^ORCID

Affiliation:

1. Department of Chemistry, Opole University, 48 Oleska Street, 45-052 Opole, Poland

2. Department of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA

Abstract

We report the cross-coupling of aryl tosylates by Ni–NHC catalysis using bulky NHC ligands. A notable feature is the combination of ‘fluoride effect’ to minimize homocoupling and IPr*MeO that enhances the activity of Ni in cross-coupling.

Funder

National Science Foundation

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY01805E

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