Photochromism in oxalatoniobates-Reference-Cited by-同舟云学术

Photochromism in oxalatoniobates

Published:2018 Issue:7 Volume:47 Page:2247-2255
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shmakova Alexandra A.¹²³⁴²,Glebov Eugeniy M.⁴²³⁵²^ORCID,Korolev Valeri V.⁴²³,Stass Dmitri V.⁴²³⁵²,Benassi Enrico⁴²³⁶⁷,Abramov Pavel A.¹²³⁴²^ORCID,Sokolov Maxim N.¹²³⁴²^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. 630090 Novosibirsk

3. Russia

4. Novosibirsk State University

5. Voevodsky Institute of Chemical Kinetics and Combustion

6. School of Science and Technology

7. Nazarbayev University

Abstract

Tris-oxalate complexes (bpyH₂)(bpyH)[NbO(C₂O₄)₃]·2H₂O, (phenH)₃[NbO(C₂O₄)₃]·3H₂O, and (2-NH₂-pyH)₃[NbO(C₂O₄)₃]·2H₂O have been isolated and fully characterised. The bipyridinium salt demonstrates remarkable photoactivity even under irradiation by daylight. The mechanism of the photoactivity was studied by diffuse reflectance spectra, EPR and quantum-chemical calculations.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04077F

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