What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?-Reference-Cited by-同舟云学术

What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

Published:2015 Issue:3 Volume:6 Page:1895-1904
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Vummaleti Sai V. C.¹²³⁴⁵,Nelson David J.⁶⁷⁸⁹¹⁰,Poater Albert¹¹¹²¹³¹⁴¹⁵,Gómez-Suárez Adrián⁶⁷⁸⁹,Cordes David B.⁶⁷⁸⁹,Slawin Alexandra M. Z.⁶⁷⁸⁹,Nolan Steven P.⁶⁷⁸⁹,Cavallo Luigi¹²³⁴⁵

Affiliation:

1. KAUST Catalyst Center

2. Physical Sciences and Engineering Division

3. King Abdullah University of Science and Technology

4. Thuwal

5. Saudi Arabia

6. EaStCHEM School of Chemistry

7. University of St Andrews

8. St Andrews

9. UK

10. WestCHEM Department of Pure and Applied Chemistry

11. Institut de Química Computacional i Catàlisi and Department de Química

12. Universitat de Girona

13. Campus de Motilivi

14. Girona

15. Spain

Abstract

The relationship between the NMR chemical shifts of phosphinidene and selenourea compounds and the π-accepting ability of the related carbene ligands has been investigated.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03264K

Reference42 articles.

1. An overview of N-heterocyclic carbenes

2. N-Heterocyclic Carbenes in Late Transition Metal Catalysis

3. N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis