Rhodium(triphenylphosphine)carbonyl-2,4-dioxo-3-pentyl-4-decanyloxybenzoate: synthesis, electrochemistry and oxidative addition kinetics
Author:
Affiliation:
1. Department of Chemistry
2. University of the Free State
3. 9300 Bloemfontein
4. Republic of South Africa
Abstract
The influence of a sterically large ligand (CH3COC(C10H21OC6H4COO)COCH3)−, substituted on complex [Rh(CH3COC(C10H21OC6H4COO)COCH3)(CO)(PPh3)], on the ease of rhodium oxidation, is described.
Funder
National Research Foundation
Universiteit van die Vrystaat
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ05039A
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3. 600. Dicarbonyl-β-diketonato- and related complexes of rhodium(I)
4. The crystal and molecular structures of acetylacetonatobiscarbonyl-rhodium(I) and of some fluoro-substituted complexes
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