On the understanding of BF3·Et2O-promoted intra- and intermolecular amination and oxygenation of unfunctionalized olefins
Author:
Affiliation:
1. State Key Laboratory of Medicinal Chemical Biology
2. College of Pharmacy
3. Tianjin Key Laboratory of Molecular Drug Research
4. Nankai University
5. Tianjin 300071
Abstract
BF3·Et2O was found to be effective for the amination and oxygenation of unfunctionalized olefins. In the presence of 3 equiv. of BF3·Et2O, intra- and intermolecular amination and oxygenation reactions could be realized in up to 99% isolated yields.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA10513G
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