Parahydrogen enhanced NMR reveals correlations in selective hydrogenation of triple bonds over supported Pt catalyst-Reference-Cited by-同舟云学术

Parahydrogen enhanced NMR reveals correlations in selective hydrogenation of triple bonds over supported Pt catalyst

Published:2015 Issue:39 Volume:17 Page:26121-26129
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhou Ronghui¹²³⁴,Cheng Wei⁵²³⁴,Neal Luke M.⁵²³⁴⁶,Zhao Evan W.¹²³⁴,Ludden Kaylee¹²³⁴,Hagelin-Weaver Helena E.⁵²³⁴,Bowers Clifford R.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Florida

3. Gainesville

4. USA

5. Department of Chemical Engineering

6. Department of Chemical & Biomolecular Engineering

Abstract

The surface processes resulting in the correlation of semi-hydrogenation selectivity and stereoselective addition to propyne are revealed by parahydrogen enhanced NMR.

Funder

Division of Chemistry

American Chemical Society

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP04223B

Reference48 articles.

1. Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance

2. Parahydrogen and synthesis allow dramatically enhanced nuclear alignment

3. Para hydrogen induced polarization in hydrogenation reactions

4. Net NMR alignment by adiabatic transport of parahydrogen addition products to high magnetic field

5. Parahydrogen-induced polarization: a new spin on reactions with molecular hydrogen

Cited by 30 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The experimental approach for the interleaved joint modulation of PHIP and NMR;The Journal of Chemical Physics;2023-11-08

2. Spatially Resolved NMR Spectroscopy for Operando Studies of Heterogeneous Hydrogenation with Parahydrogen;Applied Magnetic Resonance;2023-08-09

3. Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies;Journal of the American Chemical Society;2023-01-23

4. Mesoporous Silica Encapsulated Platinum–Tin Intermetallic Nanoparticles Catalyze Hydrogenation with an Unprecedented 20% Pairwise Selectivity for Parahydrogen Enhanced Nuclear Magnetic Resonance;The Journal of Physical Chemistry Letters;2022-05-04

5. Mechanisms of Methylenecyclobutane Hydrogenation over Supported Metal Catalysts Studied by Parahydrogen‐Induced Polarization Technique;ChemPhysChem;2022-03-08