Exploring the dynamics of Zr-based metal–organic frameworks containing mechanically interlocked molecular shuttles
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of Windsor
3. Ontario
4. Canada
5. School of Chemistry
6. Sun Yat-Sen University
7. Guangzhou
8. P. R. China
9. Florida State University
10. Tallahassee
11. USA
Abstract
MOFs UiO-68 and PCN-57, containing triphenylene linkers, were doped with a tetracarboxylate linker that contains a [2]rotaxane molecular shuttle, and VT CP MAS 13C SSNMR was used to explore the motion of the macrocyclic ring inside the cavities.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/FD/D0FD00004C
Reference34 articles.
1. A mechanically interlocked molecular system programmed for the delivery of an anticancer drug
2. A hyperbranched, rotaxane-type mechanically interlocked polymer
3. A Switchable [2]Rotaxane Asymmetric Organocatalyst That Utilizes an Acyclic Chiral Secondary Amine
4. Switching between Anion-Binding Catalysis and Aminocatalysis with a Rotaxane Dual-Function Catalyst
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