Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination

Author:

Al Mousawi Assi12345,Arar Ahmad123,Ibrahim-Ouali Malika678910,Duval Sylvain111213143ORCID,Dumur Frédéric6715163ORCID,Garra Patxi123ORCID,Toufaily Joumana45171819,Hamieh Tayssir45171819,Graff Bernadette123,Gigmes Didier6715163,Fouassier Jean-Pierre123,Lalevée Jacques123ORCID

Affiliation:

1. Institut de Science des Matériaux de Mulhouse IS2M – UMR CNRS 7361 – UHA

2. 68057 Mulhouse Cedex

3. France

4. Laboratoire de Matériaux

5. Catalyse

6. Aix Marseille Univ

7. CNRS

8. Centrale Marseille

9. iSm2

10. Marseille

11. Unité de Catalyse et Chimie du Solide (UCCS) – UMR CNRS 8181

12. Université de Lille

13. ENSCL

14. 59652 Villeneuve d'Ascq

15. ICR UMR 7273

16. F-13397 Marseille

17. Environnement et Méthodes analytiques (MCEMA-CHAMSI)

18. EDST

19. Université Libanaise

Abstract

Six new carbazole based compounds are synthesized and proposed as high performance photoinitiators for both the free radical polymerization of acrylates and the cationic polymerization of epoxides.

Funder

Agence Nationale de la Recherche

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Reference17 articles.

1. J.-P. Fouassier and J.Lalevée , Photoinitiators for Polymer Synthesis, Scope, Reactivity, and Efficiency , Wiley-VCH Verlag GmbH & Co.KGaA , Weinheim , 2012

2. J.-P. Fouassier , Photoinitiator, Photopolymerization and Photocuring: Fundamentals and Applications , Hanser , Cincinnati , Gardner Publications, New York, 1995

3. K. A. Dietliker , Compilation of Photoinitiators Commercially Available for UV Today , Sita Technology Ltd , Edinbergh, London , 2002

4. S. Davidson , Exploring the Science, Technology and Application of UV and EB Curing , Sita Technology Ltd , London , 1999

5. Photoinduced Free Radical Promoted Copper(I)-Catalyzed Click Chemistry for Macromolecular Syntheses

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