The impact of sulfur functionalisation on nitrogen-based ionic liquid cations

Author:

Santos Ana R.123ORCID,Hanson-Heine Magnus W. D.123,Besley Nicholas A.123ORCID,Licence Peter123ORCID

Affiliation:

1. GSK Carbon Neutral Laboratories, School of Chemistry, The University of Nottingham

2. Nottingham

3. UK

Abstract

XPS is used to investigate the impact of sulfur containing substituents on the electronic structure of a series of N-based cations, all with a common anion, [NTf2]. The experimental data is complex and cannot be easily deconstructed, DFT provides critical insight into bonding and electronic structure for each system studied.

Funder

Engineering and Physical Sciences Research Council

Biotechnology and Biological Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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