Thermodynamic and kinetic studies of H2 and N2 binding to bimetallic nickel-group 13 complexes and neutron structure of a Ni(η2-H2) adduct-Reference-Cited by-同舟云学术

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Thermodynamic and kinetic studies of H2 and N2 binding to bimetallic nickel-group 13 complexes and neutron structure of a Ni(η2-H2) adduct

Published:2019 Issue:29 Volume:10 Page:7029-7042
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cammarota Ryan C.¹²³⁴,Xie Jing¹²³⁴⁵^ORCID,Burgess Samantha A.⁶⁷⁸⁴^ORCID,Vollmer Matthew V.¹²³⁴,Vogiatzis Konstantinos D.¹²³⁴⁵^ORCID,Ye Jingyun¹²³⁴⁵^ORCID,Linehan John C.⁶⁷⁸⁴^ORCID,Appel Aaron M.⁶⁷⁸⁴^ORCID,Hoffmann Christina⁹¹⁰¹¹⁴^ORCID,Wang Xiaoping⁹¹⁰¹¹⁴^ORCID,Young Victor G.¹²³⁴,Lu Connie C.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Minnesota-Twin Cities

3. Minneapolis

4. USA

5. Supercomputing Institute

6. Catalysis Science Group

7. Pacific Northwest National Laboratory

8. Richland

9. Neutron Scattering Division

10. Oak Ridge National Laboratory

11. Oak Ridge

Abstract

Binding energies for H₂ and N₂ at nickel become more exergonic for the larger group 13 sigma-accepting supports.

Funder

U.S. Department of Energy

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02018G

Reference88 articles.

1. First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

2. Hydride & dihydrogen complexes of earth abundant metals: structure, reactivity, and applications to catalysis

3. Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

4. Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

5. Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays

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