One-step catalytic upgrading of bio-based furfural to γ-valerolactone actuated by coordination organophosphate

One-step catalytic upgrading of bio-based furfural to γ-valerolactone actuated by coordination organophosphate–Hf polymers

Published:2022 Issue:2 Volume:6 Page:484-501
ISSN:2398-4902
Container-title:Sustainable Energy & Fuels
language:en
Short-container-title:Sustainable Energy Fuels

Author:

Tan Jinyu¹²,Liu Yixuan¹,Li Mingrui¹,Li Hu¹^ORCID,Yang Song¹^ORCID

Affiliation:

1. State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, State Local Joint Engineering Laboratory for Comprehensive Utilization of Biomass, Center for R&D of Fine Chemicals, Guizhou University, Guiyang, China

2. Institute of Crop Germplasm Resources, Guizhou Academy of Agricultural Sciences, Guiyang, China

Abstract

A novel coordination organophosphate–Hf polymer with spherical porous structure, large surface area, and high Lewis/Brønsted acid density exhibits superior activity for one-pot cascade conversion of furfural to γ-valerolactone (81% yield).

Funder

National Natural Science Foundation of China

Fok Ying Tung Education Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SE/D1SE01476E

Reference59 articles.

1. HZ-ZrP Catalysts with Adjustable Ratio of Brønsted and Lewis Acids for the One-Pot Value-Added Conversion of Biomass-Derived Furfural

2. A combo Zr-HY and Al-HY zeolite catalysts for the one-pot cascade transformation of biomass-derived furfural to γ-valerolactone