A ferroelastic molecular rotor crystal showing inverse temperature symmetry breaking

Author:

Miao Le-Ping1234,Chu Lin-Lin56784,Han Xiang-Bin1234ORCID,Liang Bei-Dou1234,Chai Chao-Yang1234,Fan Chang-Chun1234,Wang Xiao-Xu91011124ORCID,Yao Ye-Feng56784ORCID,Zhang Wen1234ORCID

Affiliation:

1. Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics and School of Chemistry and Chemical Engineering

2. Southeast University

3. Nanjing 211189

4. China

5. Department of Physics & Shanghai Key Laboratory of Magnetic Resonance

6. School of Physics and Materials Science

7. East China Normal University

8. Shanghai 200062

9. Beijing Key Laboratory of Cloud Computing Key Technology and Application

10. Beijing Computing Center

11. Beijing Academy of Science and Technology

12. Beijing 100094

Abstract

A molecular rotor crystal shows a ferroelastic phase transition with unique inverse temperature symmetry breaking which is a result of concerted molecular movement triggered by anisotropic steric repulsion among adjacent molecules.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

East China Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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