Photochemical reactivity of phenyl (methyl-tetrazolyl) ketone – hydrogen atom transfer vs. electron transfer
Author:
Affiliation:
1. Université Clermont Auvergne
2. CNRS
3. SIGMA Clermont
4. ICCF
5. F-63000 Clermont-Ferrand
6. Université de Reims Champagne-Ardenne
7. ICMR
8. Equipe de Photochimie
9. UFR Sciences
Abstract
A novel photochemical electron transfer step is observed when a heteroaromatic substituent is present in an aromatic ketone.
Funder
Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ03061A
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1. Phototransformation of tetrazoline oxime ethers: photoisomerization vs. photodegradation
2. Phototransformation of tetrazoline oxime ethers – part 2: theoretical investigation
3. Generation of hazardous methyl azide and its application to synthesis of a key-intermediate of picarbutrazox, a new potent pesticide in flow
4. Electron and hydrogen transfer in organic photochemical reactions
5. Photochemical Electron and Hydrogen Transfer in Organic Synthesis: The Control of Selectivity
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