Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?
Author:
Affiliation:
1. POLYMAT
2. University of the Basque Country UPV/EHU
3. Joxe Mari Korta Center
4. 20018 Donostia-San Sebastián
5. Spain
6. Departamento de Química Inorgánica
7. Universidad del País Vasco UPV/EHU
8. Bilbao
Abstract
Evidence is presented that shows Lewis acid-surfactant complex catalyzed polymerization proceeds via a radical, not a cationic, mechanism.
Funder
Ministerio de Economía y Competitividad
Ekonomiaren Garapen eta Lehiakortasun Saila, Eusko Jaurlaritza
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY00363H
Reference56 articles.
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3. Stereoregulation in cationic polymerization by designed Lewis acids. II. Effects of alkyl vinyl ether structure
4. Control of Molecular Weight and Tacticity in Stereospecific Living Cationic Polymerization of α-Methylstyrene at 0 °C Using FeCl3 -Based Initiators: Effect of Tacticity on Thermal Properties
5. Isoprene Polymerization with Yttrium Amidinate Catalysts: Switching the Regio- and Stereoselectivity by Addition of AlMe3
Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Comment on “Lewis acid-surfactant complex catalysed polymerisation in aqueous dispersed media: cationic or radical polymerisation?” by A. Destephen, L. Lezama and N. Ballard, Polym. Chem., 2020, 11, 5757;Polymer Chemistry;2024
2. Reply to the ‘Comment on “Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?”’ by I. V. Vasilenko, F. Ganachaud and S. V. Kostjuk, Polym. Chem., 2024, 15, DOI: 10.1039/D3PY00661A;Polymer Chemistry;2024
3. Achieving high molecular weight alternating copolymers of 1-octene with methyl acrylate via Lewis acid catalyzed copolymerization;RSC Advances;2024
4. Water compatible silica supported iron trifluoroacetate and trichloroacetate: as prominent and recyclable Lewis acid catalysts for solvent-free green synthesis of hexahydroquinoline-3-carboxamides;RSC Advances;2023
5. On the limitations of cationic polymerization of vinyl monomers in aqueous dispersed media;Polymer Chemistry;2021
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