Formation and decomplexation kinetics of copper(ii) complexes with cyclen derivatives having mixed carboxylate and phosphonate pendant arms-Reference-Cited by-同舟云学术

Formation and decomplexation kinetics of copper(ii) complexes with cyclen derivatives having mixed carboxylate and phosphonate pendant arms

Published:2016 Issue:32 Volume:45 Page:12723-12733
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ševčík R.¹²³⁴⁵,Vaněk J.¹²³⁴⁵,Michalicová R.¹²³⁴⁵,Lubal P.¹²³⁴⁵,Hermann P.⁶²⁷⁸⁵,Santos I. C.⁹¹⁰¹¹¹²¹³,Santos I.⁹¹⁰¹¹¹²¹³,Campello M. P. C.⁹¹⁰¹¹¹²¹³

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Masaryk University

4. 611 37 Brno

5. Czech Republic

6. Department of Inorganic Chemistry

7. Universita Karlova (Charles University)

8. 128 40 Prague 2

9. Centro de Ciências e Tecnologias Nucleares

10. Instituto Superior Técnico

11. Universidade de Lisboa

12. 2695-066 Bobadela LRS

13. Portugal

Abstract

An increasing number of phosphonate pendant arms in DOTA-like ligand leads to a slightly faster complexation of Cu²⁺ion, but has a detrimental influence on the kinetic inertness of the Cu²⁺complexes of these ligands.

Funder

Czech Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01127F

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