An expeditive and green chemo-enzymatic route to diester sinapoyl-<scp>l</scp>-malate analogues: sustainable bioinspired and biosourced UV filters and molecular heaters-Reference-Cited by-同舟云学术

An expeditive and green chemo-enzymatic route to diester sinapoyl-l-malate analogues: sustainable bioinspired and biosourced UV filters and molecular heaters

Published:2023 Issue:47 Volume:14 Page:13962-13978
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rioux Benjamin¹^ORCID,Mouterde Louis M. M.¹^ORCID,Alarcan Jimmy²,Abiola Temitope T.³⁴^ORCID,Vink Matthias J. A.⁵^ORCID,Woolley Jack M.³^ORCID,Peru Aurélien A. M.¹,Mention Matthieu M.¹^ORCID,Brunissen Fanny¹^ORCID,Berden Giel⁵^ORCID,Oomens Jos⁵^ORCID,Braeuning Albert²,Stavros Vasilios G.³⁶^ORCID,Allais Florent¹^ORCID

Affiliation:

1. URD Agro-Biotechnologies Industrielles (ABI), CEBB, AgroParisTech, 51110, Pomacle, France

2. Department of Food Safety, German Federal Institute for Risk Assessment, Max-Dohrn-Str. 8-10, 10589, Berlin, Germany

3. Department of Chemistry, University of Warwick, Gibbet Hill Road, CV4 7AL, Coventry, UK

4. Department of Chemistry, Lash Miller Chemical Laboratories, 80 St. George Street, Toronto, ON, M5S 3H6, Canada

5. Institute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7, 6525ED, Nijmegen, Netherlands

6. School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK

Abstract

A highly regioselective lipase-catalyzed transesterification enabled the synthesis of sinapoyl malate diesters with fatty chains that proved to be exceptional UV filters and molecular heaters for plants.

Funder

H2020 Future and Emerging Technologies

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Agence Nationale de la Recherche

University of Warwick

Conseil départemental de la Marne

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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