Computational and experimental studies on Cu/Au-catalyzed stereoselective synthesis of 1,3-disubstituted allenes-Reference-Cited by-同舟云学术

Computational and experimental studies on Cu/Au-catalyzed stereoselective synthesis of 1,3-disubstituted allenes

Published:2019 Issue:11 Volume:6 Page:1780-1786
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Cid María Magdalena¹²³⁴^ORCID,Lago-Silva María¹²³⁴,Comesaña Marta González¹²³⁴,Nieto Faza Olalla¹²³⁴^ORCID,López Carlos Silva¹²³⁴^ORCID

Affiliation:

1. Departamento de Química Orgánica

2. Universidade de Vigo

3. 36310 Vigo

4. Spain

Abstract

Thorough mechanistic investigation unveils details of the allenylation of terminal alkynes (ATA) under Crabbé-like conditions allowing for an enantioselective approach.

Funder

Ministerio de Ciencia e Innovación

Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00364A

Reference41 articles.

1. Allenes in Molecular Materials

2. Synthesis and Properties of Allenic Natural Products and Pharmaceuticals

3. Allene Cross-Metathesis: Synthesis of 1,3-Disubstituted Allenes

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