Electronic effects in the dissociative ionisation of pyrene clusters

Author:

Garcia Gustavo A.1ORCID,Dontot Léo23,Rapacioli Mathias3,Spiegelman Fernand3,Bréchignac Philippe4,Nahon Laurent1ORCID,Joblin Christine2ORCID

Affiliation:

1. Synchrotron SOLEIL, L’Orme des Merisiers, Départamentale 128, 91190 Saint Aubin, France

2. Institut de Recherche en Astrophysique et Planétologie, Université de Toulouse III – Paul Sabatier, CNRS, CNES, 9 avenue du Colonel Roche, BP 44346, F-31028 Toulouse, France

3. Laboratoire de Chimie et Physique Quantiques, FERMI, Université de Toulouse III – Paul Sabatier, CNRS, 118 Route de Narbonne, F-31062 Toulouse, France

4. Institut des Sciences Moléculaires d’Orsay, CNRS, Université Paris-Saclay, F-91405 Orsay, France

Abstract

We present a combined experimental and theoretical study on the dissociative ionisation of clusters of pyrene that shows non-statistical behaviour and suggests that the role of excited states must be considered in the interpretation of the results.

Funder

Agence Nationale de la Recherche

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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