Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent-Reference-Cited by-同舟云学术

Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent

Published:2019 Issue:13 Volume:55 Page:1927-1930
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zatsepin Pavel¹²³⁴^ORCID,Ahn Seihwan⁵⁶⁷⁸⁹^ORCID,Pudasaini Bimal⁵⁶⁷⁸⁹^ORCID,Gau Michael R.¹²³⁴,Baik Mu-Hyun⁵⁶⁷⁸⁹^ORCID,Mindiola Daniel J.¹²³⁴^ORCID

Affiliation:

1. University of Pennsylvania

2. Chemistry

3. Philadelphia

4. USA

5. Department of Chemistry

6. Korea Advanced Institute of Science and Technology (KAIST)

7. Daejeon 34141

8. Republic of Korea

9. Institute for Basic Science (IBS)

Abstract

Cp*(Me₃P)Ir(CH₃)(OTf), a complex known to reversibly activate CH₄ and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H₂CPPh₃ in THF to afford two major species [Cp*(Me₃P)(Ph₃P)Ir(CH₂CH₃)][OTf] and [Cp*(Me₃P)Ir(H)(η²-CH₂CH₂)][OTf].

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC08761J

Reference20 articles.

1. Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf)

2. Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solution

3. Cationic Ir(III) Alkylidenes Are Key Intermediates in C–H Bond Activation and C–C Bond-Forming Reactions

4. Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic MIII Alkylidenes

5. Cross-Coupling of α-Carbonyl Sulfoxonium Ylides with C−H Bonds

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