Hydroboration of terminal olefins with pinacolborane catalyzed by new 2-iminopyrrolyl iron(ii) complexes
Author:
Affiliation:
1. Centro de Química Estrutural
2. Departamento de Engenharia Química
3. Instituto Superior Técnico
4. Universidade de Lisboa
5. 1049-001 Lisboa
6. C2TN-Centro de Ciências e Tecnologias Nucleares
7. 2695-066 Bobadela LRS
8. Portugal
Abstract
New Fe(ii) mono(2-iminopyrrolyl) complexes catalyze the hydroboration of terminal olefins with pinacolborane via a borane oxidative addition pathway.
Funder
Fundação para a Ciência e a Tecnologia
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CY/C8CY02319K
Reference110 articles.
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2. New homogeneous rhodium catalysts for the regioselective hydroboration of alkenes
3. Reactions of catecholborane with Wilkinson's catalyst: implications for transition metal-catalyzed hydroborations of alkenes
4. Transition metal-catalyzed addition of catecholborane to .alpha.-substituted vinylarenes: hydroboration vs dehydrogenative borylation
5. Recent Advances in Organic Synthesis Using Transition Metal-Catalyzed Hydroborations
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