The role of carboxylato ligand dissociation in the oxidation of chrysin with H2O2 catalysed by [Mn2III,IV(μ-CH3COO)(μ-O)2(Me4dtne)](PF6)2
Author:
Affiliation:
1. Stratingh Institute for Chemistry
2. Faculty of Mathematics and Natural Sciences
3. University of Groningen
4. , The Netherlands
5. Catexel Ltd
6. BioPartner Center Leiden
7. 2333 BD Leiden, The Netherlands
Abstract
The loss of the acetato ligand is shown to be key to the activity of this manganese catalyst at pH 11 in bleaching of chrysin.
Funder
European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53174K
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3. Dinuclear Manganese(II,III,IV) Model Complexes for the Active Center of the Metalloprotein Photosystem II: Synthesis, Magnetism, and Crystal Structure of [LMnIII(?-O)(?-CH3CO2)2MnIVL][ClO4]3 (L = N,N?N?-Trimethyl-1,4,7-triazacyclononane)
4. Coordination chemistry of the bimacrocyclic, potentially binucleating ligand 1,2-bis(1,4,7-triaza-1-cyclononyl)ethane (dtne). Electrochemistry of its first transition series metal(II,III) complexes. Characterization of the new hemerythrin model complex [Fe2(dtne)(.mu.-O)(.mu.-CH3CO2)2]Br2.H2O
5. A novel mixed-valent MnIII–MnIV-dimer, [L2Mn2(µ-O)2(µ-MeCO2)][BPh4]2·MeCN: crystal structure, magnetic properties, and e.s.r. spectrum (L = 1,4,7-triazacyclononane)
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