Experimental evidence for the elusive ketohydroperoxide pathway and the formation of glyoxal in ethylene ozonolysis-Reference-Cited by-同舟云学术

Experimental evidence for the elusive ketohydroperoxide pathway and the formation of glyoxal in ethylene ozonolysis

Published:2022 Issue:94 Volume:58 Page:13139-13142
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lewin Caroline Smith¹,Herbinet Olivier¹^ORCID,Garcia Gustavo A.²^ORCID,Arnoux Philippe¹,Tran Luc-Sy³,Vanhove Guillaume³^ORCID,Nahon Laurent²^ORCID,Battin-Leclerc Frédérique¹^ORCID,Bourgalais Jérémy¹^ORCID

Affiliation:

1. Université de Lorraine, CNRS, LRGP, F-54000 Nancy, France

2. Synchrotron SOLEIL, L’Orme des merisiers, Saint-Aubin-BP 48, 91192 Gif-sur-Yvette Cedex, France

3. Université Lille, CNRS, UMR 8522 – PC2A – Physicochimie des Processus de Combustion et de l’Atmosphère, F-59000 Lille, France

Abstract

Despite decades of research, an unambiguous kinetic network in ethylene ozonolysis remain elusive. This experimental work demonstrates that a substantial fraction of the primary ozonide leads to 2-hydroperoxyacetaldehyde which decomposes to glyoxal.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05229F

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