Interfacial self-assembly of SiO2–PNIPAM core–shell particles with varied crosslinking density

Author:

Ickler Maret12,Menath Johannes12ORCID,Holstein Laura12,Rey Marcel123ORCID,Buzza D. Martin A.4ORCID,Vogel Nicolas12ORCID

Affiliation:

1. Institute of Particle Technology (LFG), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Cauerstrasse 4, 91058 Erlangen, Germany

2. Interdisciplinary Center for Functional Particle Systems (FPS), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Haberstrasse 9a, 91058 Erlangen, Germany

3. School of Physics & Astronomy, The University of Edinburgh, Peter Guthrie Tait Road, Edinburgh, EH9 3FD, UK

4. G W Gray Centre for Advanced Materials, Department of Physics & Mathematics, University of Hull, Hull HU6 7RX, UK

Abstract

The effect of crosslinker content and core size on the interfacial self-assembly of batch-type PNIPAM@SiO2 core–shell particles was studied, revealing parameter windows for chain phases, rhomboid packing and stable d = 448 nm non-close packed cores.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

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