Dihalo bismuth cations: unusual coordination properties and inverse solvent effects in Lewis acidity-Reference-Cited by-同舟云学术

Dihalo bismuth cations: unusual coordination properties and inverse solvent effects in Lewis acidity

Published:2022 Issue:70 Volume:58 Page:9826-9829
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ramler Jacqueline¹,Stoy Andreas²,Preitschopf Tobias³,Kettner Janosch²,Fischer Ingo³^ORCID,Roling Bernhard²^ORCID,Fantuzzi Felipe⁴^ORCID,Lichtenberg Crispin¹²^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Julius-Maximilians-University Würzburg, Am Hubland, 97074, Würzburg, Germany

2. Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany

3. Institute of Physical and Theoretical Chemistry, Julius-Maximilians-University Würzburg, Am Hubland, 97074, Würzburg, Germany

4. School of Physical Sciences, Ingram Building, University of Kent, Park Wood Rd, Canterbury, CT2 7NH, UK

Abstract

Dihalo bismuth cations show an unusual pentagonal bipyramidal coordination geometry with a stereochemically inactive lone pair. Their relevance for the Lewis acidity of BiX3 is discussed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04017D

Reference51 articles.

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