Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N–H/P

Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N–H/P–H

Published:2017 Issue:20 Volume:19 Page:4769-4773
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Wang Yukang¹²³⁴⁵,Qian Peng¹²³⁴⁵,Su Ji-Hu⁶⁷³⁴⁵,Li Yanan¹²³⁴⁵,Bi Meixiang¹²³⁴⁵,Zha Zhenggen¹²³⁴⁵,Wang Zhiyong¹²³⁴⁵^ORCID

Affiliation:

1. Hefei National Laboratory for Physical Sciences at Microscale

2. CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry & Collaborative Innovation Center of Suzhou Nano Science and Technology

3. University of Science and Technology of China

4. Hefei

5. P. R. China

6. CAS Key Laboratory of Microscale Magnetic Resonance

7. Department of Modern Physics

Abstract

A facile and efficient approach to phosphinic amides was developed from diarylphosphine oxides and amines via electrosynthesis. A variety of phosphinic amides were obtained in one step with good to excellent yields under mild and metal-free conditions. The corresponding mechanism was investigated.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C7GC01989K

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