Base hydrolysis of αβ-nitro-, azido- and isothiocyanato-[1,9-bis(2′-pyridyl)-2,5,8-triazanonane]- and [1,11-bis(2′-pyridyl)-2,6,10-triazaundecane]-cobalt(III) cations. Departure from first-order hydroxide dependence-Reference-Cited by-同舟云学术

Base hydrolysis of αβ-nitro-, azido- and isothiocyanato-[1,9-bis(2′-pyridyl)-2,5,8-triazanonane]- and [1,11-bis(2′-pyridyl)-2,6,10-triazaundecane]-cobalt(III) cations. Departure from first-order hydroxide dependence

Published:1990 Issue:7 Volume: Page:2175-2180
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Ahmed Etmina,Tobe Martin L.,Humanes Madalena

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900002175

Reference12 articles.

1. Base-catalysed aquation of αβ-syn- and αβ-anti-chloro- and bromo-[1,9-bis(2′-pyridyl)-2,5,8-triazanonane]- and -[1,11-bis(2′-pyridyl)-2,6,10-triazaundecane]-cobalt(III) cations. An unusually base-sensitive halogenopentamine cobalt(III) system

2. The crystal and molecular structure of an isomer of Bromo [1,9-bis(2-pyridyl) 2,5,8-triazononane] cobalt(III), perchlorate, [Co(picdien)Br](ClO42and that of an isomer of nitro[1,9-bis(2-pyridyl)2,5,8-triazanonane]cobalt(III), perchlorate, [Copicdien)(No2)](ClO4)2

3. Crystal and molecular structure of chloro[1,11-bis(2-pyridyl)2,6,10-triazaundecane]cobalt(III) tetrachlorocobaltate(II) hemihydrate, [Co(picditn)Cl] CoCl4·H2O

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1. A Unique Mechanism for Base Catalyzed Hydrolysis of Pentaaminecobalt(III) Complexes Containing Picolyl Residues;Inorganic Chemistry;2003-05-13

2. Cobalt;Coordination Chemistry Reviews;1993-04

3. The structures of anti-αβ-azido- and isothiocyanato-{1,9-bis(2′-pyridyl)-2,5,8- triazanonane}cobalt(III) perchlorate and anti-αβ- isothiocyanato-{1,11-bis(2′-pyridyl)-2,6,10-triazaundecane}cobalt(III) perchlorate;Polyhedron;1991-01

4. ChemInform Abstract: Base Hydrolysis of αβ-Nitro-, Azido- and Isothiocyanato-(1,9-bis(2′-pyridyl)-2,5,8-triazanonane)- and (1,11-Bis(2′-Pyridyl)-2,6,10-triazaundecane)-cobalt(III) Cations. Departure from First-Order Hydroxide Dependence.;ChemInform;1990-10-02