Synthesis and characterisation of binuclear and trinuclear organoimido complexes of tungsten-(VI) and -(V) and a binuclear tungsten(V) oxoanion. X-Ray crystal structures of [{WCl4(NEt)}2], [P(CH2Ph)Ph3][W3Cl7(NBut)3(µ-NPh)3], [P(CH2Ph)Ph3][W2Cl7(NR)2](R = Et or Ph), and [P(CH2Ph)Ph3][W2O2Cl7]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900001043
Reference34 articles.
1. Organoimido-complexes of tungsten-(VI)-(V), and -(IV) : crystal and molecular structures of [W(NPh)Cl3(PPh3)2] and [W(NPh)Cl2(PMe3)3]
2. The crystal structure of an oxidation product from the reaction between tungsten(V) chloride and trichloroacetonitrile
3. Studies of π-bonding perturbation in the tungsten-nitrogen multiple bond of isopropylimido tungsten(VI) complexes: The crystal and molecular structures of [W(NCHMe2)Cl4]2·C6H6 and [W(NCHMe2)Cl5][NEt4]
4. Structure of di-μ-chloro-bis[trichloro(p-tolylimino)tungsten(VI)], [{WCl3(p-CH3C6H4N)}2(μ-Cl)2]
5. Preparation and characterisation of mononuclear organoimido complexes of tungsten: X-ray crystal structures of [WCl4(NC6H4Me-p)(thf)], [P(CH2Ph)Ph3][WCl5(NC6H4Me-p)], and [WCl2(NPh)2(bipy)]
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