Synthesis of intermediates in the C–H activation of acetone with 2-phenylazophenylgold(III) complexes and in the C–C coupling of aryl groups from diarylgold(III) complexes. Crystal and molecular structures of [Au{C6H3(NNC6H4Me-4′)-2-Me-5}(acac-C)Cl](acac = acetylacetonate), cis-[Au(C6H4NNPh-2)Cl2(PPh3)], and [Au(C6H4CH2NMe2-2)(C6F5)Cl]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900003083
Reference17 articles.
1. C–H activation of acetone by 2-phenylazophenylgold(III) complexes; synthesis of the first acetonylgold(III) complex
2. Synthesis of the first acetonylgold(III) complexes by C–H activation of acetone with 2-phenylazophenylgold(III) complexes
3. Synthesis of [2-{(dimethylamino)methyl} phenyl]-(2-nitrophenyl)gold(III) complexes
4. Bifunctional activation of ketone with rhodium(III) porphyrin. Efficient cooperation of metal and intramolecular base
5. Catalytic reactions of metalloporphyrins.
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