Total synthesis of naturally occurring abietane diterpenoids via a late-stage Fe(<scp>iii</scp>)-bTAML catalysed Csp3–H functionalization-Reference-Cited by-同舟云学术

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Total synthesis of naturally occurring abietane diterpenoids via a late-stage Fe(iii)-bTAML catalysed Csp³–H functionalization

Published:2024 Issue:28 Volume:14 Page:20420-20424
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Munda Mintu¹^ORCID,Chatterjee Debasmita²^ORCID,Majhi Moumita²,Biswas Souvik²,Pal Debopam²^ORCID,Bisai Alakesh¹²^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhauri, Bhopal-462 066, Madhya Pradesh, India

2. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, Nadia-741 246, West Bengal, India

Abstract

A site-selective C–H functionalization strategy has been developed for a concise total synthesis of angustanol (5), majusanin B (2), majusanic acid D (1), angustanoic acid F (4), angustanoic acid E (6) and angustanoic acid G (3).

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA03791J

Reference56 articles.

1. Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

2. Iron Catalysis in Organic Synthesis

3. Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates

4. Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

5. Biologically inspired oxidation catalysis

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