A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce2P2W16O60L2}n zipper chains

Author:

Wang Wenyan1ORCID,Izarova Natalya V.12ORCID,van Leusen Jan1ORCID,Kögerler Paul12ORCID

Affiliation:

1. Institute of Inorganic Chemistry, RWTH Aachen University, D-52074 Aachen, Germany

2. Jülich-Aachen Research Alliance (JARA-FIT), Peter Grünberg Institute 6, Forschungszentrum Jülich, D-52425 Jülich, Germany

Abstract

The first coordination polymer of a polyoxometalate bi-functionalized by phosphonate and lanthanoid groups forms when {CeIII22,-PV2WVI16O60)L2} units are joined by direct inter-cluster Ce–OW bonds into 1D chains.

Funder

FP7 Ideas: European Research Council

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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