Replication of a synthetic oligomer using chameleon base-pairs

Author:

Núñez-Villanueva Diego1ORCID,Hunter Christopher A.1ORCID

Affiliation:

1. Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK

Abstract

An oligomer equipped with benzoic acid recognition units templates the polymerization of monomers with amidine recognition units, but cleavage of ester linkers in the resulting copy transforms the amidine recognition units into benzoic acids.

Funder

H2020 European Research Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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2. Synthetically encoded complementary oligomers;Nature Reviews Chemistry;2023-11-16

3. [closo-B10H8-1,10-(NHC( NH2)Me)2]: A rare zwitterionic amidinium derivative;Journal of Molecular Structure;2023-07

4. Engineering precise sequence-defined polymers for advanced functions;Progress in Polymer Science;2023-06

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