New insights into the asymmetric Diels–Alder reaction: the endo- and S-selective retro-Diels

New insights into the asymmetric Diels–Alder reaction: the endo- and S-selective retro-Diels–Alder reaction

Published:2015 Issue:128 Volume:5 Page:106234-106238
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Na¹²³⁴⁵,Liang Xianrui¹²³⁴⁵,Su Weike¹²³⁴

Affiliation:

1. Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals

2. Zhejiang University of Technology

3. Hangzhou 310014

4. China

5. College of Pharmaceutical Sciences

Abstract

The endo- and S-selective retro-Diels–Alder reactions have been proposed and verified in an imidazolethione-catalyzed asymmetric Diels–Alder reaction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA17788J

Reference70 articles.

1. Catalytic Asymmetric Total Synthesis of (+)-Yohimbine

2. Recent Advances in Natural Product Synthesis by Using Intramolecular Diels−Alder Reactions

3. The Diels-Alder Reaction in Total Synthesis

4. Catalytic Enantioselective Diels-Alder Reactions: Methods, Mechanistic Fundamentals, Pathways, and Applications

5. Total Synthesis of taxol. 2. Construction of A and C ring intermediates and initial attempts to construct the ABC ring system

Cited by 8 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Nucleophilicity of 4‐(Alkylthio)‐3‐imidazoline Derived Enamines;Chemistry – A European Journal;2023-11-15

2. The effect of S-alkylation on organocatalytic enamine activation through imidazolidine-4-thiones;Chemical Communications;2023

3. Structure and Bonding of 1,2,4-Triazole Thiones Derived from Nitron;Journal of Molecular Structure;2021-05

4. Stereoselective Synthesis by Catalysts Supported on Magnetic Nanoferrite;Catalyst Immobilization;2019-12-20

5. Novel binaphthyl and biphenyl α- and β-amino acids and esters: organocatalysis of asymmetric Diels–Alder reactions. A combined synthetic and computational study;Organic & Biomolecular Chemistry;2018