Rhodium-catalyzed highly diastereoselective intramolecular [4 + 2] cycloaddition of 1,3-disubstituted allene-1,3-dienes-Reference-Cited by-同舟云学术

Rhodium-catalyzed highly diastereoselective intramolecular [4 + 2] cycloaddition of 1,3-disubstituted allene-1,3-dienes

Published:2018 Issue:18 Volume:5 Page:2680-2684
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Han Yulin¹²³⁴⁵,Ma Shengming¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. P. R. China

Abstract

RhCl(PPh₃)₃-catalyzed [4 + 2] intramolecular cycloaddition of allene-1,3-dienes afforded cis-fused [3.4.0]-bicyclic products with three chiral centers in good yields with excellent chemo- and diastereoselectivity.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00650D

Reference53 articles.

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5. Copper-catalyzed azide–alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(i) acetylides

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