Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate-Reference-Cited by-同舟云学术

Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate

Published:2022 Issue:45 Volume:13 Page:6284-6292
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Ivanchenko Oleksandr¹,Mazières Stéphane¹,Poli Rinaldo²^ORCID,Harrisson Simon³^ORCID,Destarac Mathias¹^ORCID

Affiliation:

1. Laboratoire des IMRCP, Université Toulouse 3 Paul Sabatier, CNRS UMR 5623, 118 route de Narbonne, 31062 Toulouse, France

2. LCC, Université de Toulouse/INPT/CNRS UMR 5623, 205 route de Narbonne, 31077 Toulouse, France

3. LCPO, Université de Bordeaux/ENSCBP/CNRS UMR 5623, 16 avenue Pey Berland, 33607 Pessac, France

Abstract

The radical ring-opening copolymerisation of unsubstituted thionolactones of different ring sizes has been investigated. DFT calculations and experimental results show the importance of the stabilization of the intermediate ring-retained radical.

Funder

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY01153K

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