Electron transfer between neptunium and sodium chlorite in acidic chloride media

Author:

Arko Brian T.12ORCID,Dan David1,Adelman Sara L.1ORCID,Kimball David B.1ORCID,Kozimor Stosh A.1ORCID,Shafer Jenifer C.2ORCID

Affiliation:

1. Los Alamos National Laboratory, Los Alamos, NM 87545, USA

2. Department of Chemistry, Colorado School of Mines, Golden, CO 90401, USA

Abstract

Redox chemistry between Np4+(aq) and NaClO2(aq) can be controlled as a function of neptunium vs. NaClO2(aq), Cl1−(aq), and H1+(aq) concentrations. Certain chemical environments held Np4+(aq) in the +4 oxidation state. Other chemical environments generated NpO21+(aq) and/or NpO22+(aq).

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference73 articles.

1. P.Paviet-Hartmann , C.Riddle , K.Campbell and E.Mausolf , Overview of Reductants Utilized in Nuclear Fuel Reprocessing/Recycling, Report INL/CON-12-28006 , Idaho National Labs , Idaho Falls, Idaho , 2013

2. Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium

3. The maturing of nuclear fuel: Past to Accident Tolerant Fuel

4. Materials challenges for nuclear systems

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