Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets

Author:

Shao Feng12345ORCID,Zhuang Jia-Jia6789,Chen Ming-Guang10115,Wang Ning121314155,Shi Hai-Yan12345,Tong Jia-Ping12345ORCID,Luo Gang6789,Tao Jun12345ORCID,Zheng Lan-Sun12345

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry

2. College of Chemistry and Chemical Engineering

3. Xiamen University

4. Xiamen 361005

5. PR China

6. Lab of Chemical Materials and Devices

7. Training Base of Army Logistics University of PLA

8. Xiangyang 441000

9. P.R. China

10. Baotou Research Institute of Rare Earths

11. Baotou 014040

12. Shenzhen Institutes of Advanced Technology

13. Chinese Academy of Sciences 1068 Xueyuan Avenue

14. Shenzhen University Town

15. Shenzhen 518000

Abstract

The work demonstrates a facile and environmentally friendly synthesis of hexanuclear clusters as cryogenic magnetic coolants and molecular magnets.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Inner Mongolia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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