Tuning the porosity of triangular supramolecular adsorbents for superior haloalkane isomer separations

Author:

Hua Bin1,Ding Yanjun1,Alimi Lukman O.1,Moosa Basem1,Zhang Gengwu1,Baslyman Walaa S.1,Sessler Jonathan2ORCID,Khashab Niveen M.1ORCID

Affiliation:

1. Smart Hybrid Materials Laboratory (SHMs), Advanced Membranes and Porous Materials Center, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

2. Department of Chemistry, The University of Texas at Austin, Austin, TX 78712-1224, USA

Abstract

The methylene-bridged trianglamine (TA) can selectively capture 1-chlorobutane from a mixture of 1-chlorobutane and 2-chlorobutane due to the greater thermodynamic stability of the TA-based host–guest complex formed with 1-chlorobutane.

Funder

King Abdullah University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference34 articles.

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2. n-BUTYL CHLORIDE

3. Gas chromatographic separation of diastereoisomeric haloalkanes and o-, m- and p-isomers of monosubstituted halobenzenes with Igepal CO-880

4. L. H.Brandsma and D.Verkruijsse , Preparative Polar Organometellic Chemistry I , Springer-Verlag , Berlin , 1987 , ISBN 3-540-16916-4

5. Iron-Catalyzed Halogenation of Alkanes: Modeling of Nonheme Halogenases by Experiment and DFT Calculations

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